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Later episodes continued to foreshadow this when Kara members attempt to steal some critical DNA that was critical in the creation of the White Zetsu army.
Source: https://screenrant.com/boruto-explained-zetsu-return-classic-naruto-villain/
One of the main antagonists of and Kaguya Otsutsuki's will incarnate, Black Zetsu managed to get his hands on the Rinnegan towards the end of the series.
That being said, they still had difficulty with Zetsu because he could use Wood Release.