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During the early parts of Battle Rewards will be the most reliable way to get Wyrrite.
Source: https://gamerant.com/ff16-xvi-final-fantasy-16-how-to-get-wyrrite/
They can purchase it for 4,000 Gil or craft the +1 version of the blade using one Sanguine Insignia, 280 Wyrrite, and 280 Magicked Ash.