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Following the end of the Earth-Romulan War and the establishment of the United Federation of Planets, Dr. Phlox found himself reassigned.
Source: https://gamerant.com/star-trek-enterprise-what-happened-dr-phlox/
The Earth-Romulan war was an important backstory for Starfleet from as far back as the TOS era, but it's never been realized on-screen in Star Trek.
Source: https://screenrant.com/star-trek-earth-romulan-war-missed-opportunity/